Matthews piles on the runs to help Harptree hammer the Bristol Sikhs
Matthews' innings included 17 boundaries and 5 sixes in Harptree's total of 295-3.
He shared a partnership of 96 for the second wicket with Rich Currell (34), and 165 for the third with skipper Andrew Fox (65).
In reply, Old England Bristol Sikhs' Rob Brown (31) and Tim Kennedy (40) were the main contributors.
Leaders Dyrham & Hinton 2nds maintained their unbeaten record with a 56-run victory at Midsomer Norton after Ashley Pearce top-scored with 96.
GWR Shunters remain rooted to the bottom after defeat by 47 runs at Bath 4ths despite Tony James taking 3-39.
In Division One, second-placed Dyrham & Hinton inflicted a massive 257-run defeat upon Old Bristolians Westbury 3rds.
Martin Millard struck 107 as Dyrham posted 325-6, their highest total of the season, and off spinner Andrew Lewis later took four wickets.
Saltford Fairway made it three home wins in succession to climb clear of the drop zone with a dramatic one-wicket win over third-placed Wrington as skipper Kevin Fletcher made 51 and Wes Taynton 56.
Backwell Flax Bourton were defeated by 61 runs at Stratton on Fosse, despite a battling 99 from Tim Martin.
Knowle West are the new leaders of Division Two after beating landlords Stanton Drew by 169 runs.
Opening batsman Rob Bailey struck an unbeaten 135, his ninth century for the club.
In reply, only Gary Smart (43) provided any resistance, and there were three wickets each for skipper Clive Bailey and Stewart Cole.
Brislington recorded their third consecutive win, beating lowly Exiles (Bath) by six wickets, to maintain their promotion push after an unbroken 113 fifth-wicket partnership between Ian Dowding (75) and Ashley Nutt (53).
Bristol 3rds recorded their first victory since the end of May with an assured six-wicket triumph over Weston super Mare 3rds.
Bristol all-rounder Richard Morrison dominated proceedings with a personal best of 87 not out, to follow up a return of 3-47.
Division Four leaders Nailsea beat nearest rivals Midsomer Norton Methodists by five wickets after Tom Hicks top-scored with an unbeaten 72.
Old Park moved further clear of the relegation area after condemning bottom of the table Grendel 2nds to their ninth defeat of the season. The Park, batting first, scored 209-6, Kerry Adams blasting 65, and opener Mark Galsworthy 46.
Matt Parfitt, for the second successive week, was Midsomer Norton 4ths' bowling hero with 4-28 as they beat Old Bristolians Westbury 4ths.
Despite scoring 226 against Shepton Mallet, Martin Wall top scoring with 76, Whitchurch A went down to a three-wicket defeat.
Joint leaders Keynsham 3rds beat Bitton by 167 runs after Richard Watkins hit 73 and James Courtney 51.
In reply, the home side were dismissed for just 109, despite a maiden League half-century for Jordan Smith (60).
Joint leaders Wrington 2nds won by seven wickets over Nailsea 4ths after Seb Williams top-scored with 57.
Easton Cowboys remain in third place after their fifth win in succession – a victory by 22 runs over Avonside. Justin Avery, with 91, and Roger Ball, 5- 41, were the orchestrators in this success.
Brislington 4ths beat Exiles (Bath) 2nds by 51 runs thanks to a fine 129-run fifth-wicket partnership between Paul Iles (77) and Charlie Peters (68).
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Martin Wall,Jordan Smith,Simon Matthews,Rob Brown,Tom Hicks,Gary Smart,Clive Bailey,Matt Parfitt,Richard Watkins,Kevin Fletcher,Rob Bailey,Mark Galsworthy,Martin Millard,Stewart Cole,Tim Martin,Andrew Lewis,Bristol,Bath,Weston,Stanton Drew

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